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Silver(I) fluoride
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Silver(I) fluoride : ウィキペディア英語版
Silver(I) fluoride

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Silver(I) fluoride is the inorganic compound with the formula AgF. It is one of the three main fluorides of silver, the others being silver subfluoride and silver(II) fluoride. AgF has relatively few niche applications; it has been employed as a fluorination and desilylation reagent in organic synthesis and in aqueous solution as a topical caries treatment in dentistry.
The hydrates of AgF present as colourless, while pure anhydrous samples are yellow.〔
== Preparation ==
High-purity silver(I) fluoride can be produced by the heating of silver carbonate to 310 °C under a hydrogen fluoride environment, in a platinum tube:
: Ag2CO3 + 2HF → 2AgF + H2O + CO2
Laboratory routes to the compound typically avoid the use of gaseous hydrogen fluoride. One method is the thermal decomposition of silver tetrafluoroborate:
:AgBF4 → AgF + BF3
In an alternative route, silver(I) oxide is dissolved in concentrated aqueous hydrofluoric acid, and the silver fluoride is precipitated out of the resulting solution by acetone.〔
: Ag2O + 2HF → 2 AgF + H2O

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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